Material Safety Data Sheet
Phosphoric acid, 85%

ACC# 18691
Section 1 - Chemical Product and Company Identification

MSDS Name: Phosphoric acid, 85%
Catalog Numbers: AC201140000, AC201140010, AC201140025, AC201140050, AC201145000, AC295700000, AC295700010, AC295700025, AC424040000, AC424040025, AC424045000, S80124, S93325, S93326, A242-1, A242-212, A242-212001, A242-4, A242-4LC, A242-500, A242FB115, A242FB19, A242FB200, A242FB50, A242J500, A242P-4, A242P-500, A242SK-212, A242SS200, A242SS28, A242SS50, A260-500, A260J500, A365-1, A365-4, A366-20, A366-4, A3664LC, NC9005659, NC9577323, NC9857172, NC9859987, NC9881301, NC9916667
Synonyms:
Orthophosphoric acid; White phosphoric acid.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7664-38-2 Phosphoric acid >85 231-633-2
7732-18-5 Water <15 231-791-2

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless viscous clear liquid.
Danger! Causes digestive and respiratory tract burns. Causes eye and skin burns. Hygroscopic (absorbs moisture from the air). Corrosive to metal.
Target Organs: Eyes, skin, mucous membranes.


Potential Health Effects
Eye: May cause irreversible eye injury. Contact with liquid is corrosive to the eyes and causes severe burns.
Skin: Contact with liquid is corrosive and causes severe burns and ulceration. The severity of injury depends on the concentration of the solution and the duration of exposure.
Ingestion: Causes gastrointestinal tract burns. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation: Causes chemical burns to the respiratory tract. Because its vapor pressure is negligible, it exists in the air only as a mist or spray.
Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures


Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid immediately.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Persons with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance. Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Substance is noncombustible. Contact with metals may evolve flammable hydrogen gas.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Spill may be carefully neutralized with lime (calcium oxide, CaO).

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from metals. Do not store in metal containers. Store protected from moisture. Store away from alkalies.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Phosphoric acid 1 mg/m3 TWA; 3 mg/m3 STEL 1 mg/m3 TWA 1000 mg/m3 IDLH 1 mg/m3 TWA
Water none listed none listed none listed

OSHA Vacated PELs: Phosphoric acid: 1 mg/m3 TWA Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical goggles and face shield.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties


Physical State: Clear liquid
Appearance: APHA: 10 max - colorless viscous
Odor: odorless
pH: 1.5 (0.1N aq. soln)
Vapor Pressure: 0.03 mm Hg @ 20 deg C
Vapor Density: 3.4 (air=1)
Evaporation Rate:Not available.
Viscosity: 3.86 mPa.s
Boiling Point: 158 deg C @ 760 mm Hg
Freezing/Melting Point:21 deg C
Decomposition Temperature:Not available.
Solubility: Miscible.
Specific Gravity/Density:1.685 g/cm3
Molecular Formula:H3O4P
Molecular Weight:98.00

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials: Metals, strong oxidizing agents, strong bases, amines, ammonia, sulfuric acid, nitromethane, sodium tetrahydroborate, A 5% solution of H3PO4 is DOT corrosive to both aluminum & carbon steel (results: 272.1 mils/yr & 319.6 mils/yr, respectively). A 4% H3PO4 solution corrodes aluminum at 209.1 mils/yr & carbon steel at 240.9 mils/yr..
Hazardous Decomposition Products: Oxides of phosphorus.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7664-38-2: TB6300000      
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7664-38-2:
     Draize test, rabbit, eye: 119 mg Severe;
     Draize test, rabbit, skin: 595 mg/24H Severe;
     Inhalation, mouse: LC50 = 25.5 mg/m3;
     Inhalation, rat: LC50 = >850 mg/m3/1H;
     Inhalation, rat: LC50 = 25.5 mg/m3;
     Oral, mouse: LD50 = 1.25 gm/kg;
     Oral, rat: LD50 = 1530 mg/kg;
     Oral, rat: LD50 = 1.25 gm/kg;
     Skin, rabbit: LD50 = 2740 mg/kg;
CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 7664-38-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: CAS# 7664-38-2: Standard Draize Test: skin, rabbit = 595 mg/24H (Severe).; Standard Draize Test: eye, rabbit = 119 mg (Severe).

Section 12 - Ecological Information


Ecotoxicity: Fish: Mosquito Fish: LC50 = 138 mg/L; 96 Hr; Unspecified No data available.
Environmental: The acidity of phosphoric acid may be reduced readily by natural water hardness minerals, but the phosphate may persist indefinitely. During transport through the soil, phosphoric acid will dissolve some of the soil material, in particular, carbonate-based materials. The acid will be neutralized to some degree with adsorption of the proton and phosphate ions also possible. However, significant amounts of acid will remain for transport down toward the groundwater table.
Physical: No information available.
Other: Dangerous to aquatic life in high concentrations.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: PHOSPHORIC ACID PHOSPHORIC ACID, LIQUID
Hazard Class: 8 8
UN Number: UN1805 UN1805
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7664-38-2 is listed on the TSCA inventory.
     CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 7664-38-2: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7664-38-2: acute.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-38-2 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7664-38-2 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     C
Risk Phrases:

     R 34 Causes burns.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)

     CAS# 7664-38-2: 1
     CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
     CAS# 7664-38-2 is listed on Canada's DSL List.
     CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of E.
Canadian Ingredient Disclosure List
     CAS# 7664-38-2 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/06/1999
Revision #6 Date: 9/16/2004

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.