Material Safety Data
Sheet
Boric Acid
ACC# 03260
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Boric Acid
Catalog Numbers: AC180570000, AC180570010, AC180570025,
AC217080000, AC217085000, AC315180000, AC315181000, AC327130000, AC327130010,
AC423480000, AC423480020, AC423485000, S79802, S79923, S79923-1, S93142, S93143,
A73-1, A73-10, A73-10LC, A73-3, A73-325LB, A73-50, A73-500, A73140KG, A74-1,
A74-10, A74-3, A74-500, A74-500LC, A77-10, A77-NHL, A78-10, A78-3, A78-50,
A78-500, A7912, A79212, AVX741, BP168-1, BP168-500, NC9107241, NC9517819,
NC9592726, NC9627238, NC9974905, XXA73PD3140KG, XXA7450KG, ZZA7321204
Synonyms: Boracic acid; Hydrogen borate; Orthoboric Acid.
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 10043-35-3 |
Boric acid |
>99.0 |
233-139-2 |
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white solid.
Warning! May cause eye and skin
irritation. May cause respiratory tract irritation. Causes digestive tract
irritation. May cause central nervous system effects. May cause adverse
reproductive effects.
Target Organs: None known.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May be absorbed through
damaged or abraded skin in harmful amounts.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause
kidney damage. May cause gastric disturbances and electrolytic imbalance. May
cause central nervous system effects. May cause cyanosis (bluish discoloration
of skin due to deficient oxygenation of the blood). CNS effects (excitement or
depression, lethargy, headache, coma, seizures), dehydration, arrhythmias, shock
and metabolic acidosis have been reported in extreme adult and pediatric cases.
Inhalation: May cause respiratory tract irritation. The
toxicological properties of this substance have not been fully investigated. May
cause irritation of the mucous membranes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic poisoning by
boron compounds, borism, may be little more than dry skin and mucous membranes,
followed by appearance of a red tongue, patchy alopecia (hair loss), cracked
lips, and conjunctivitis. Infants and young children are more susceptible to
boric acid poisoning than adults. May cause adverse reproductive effects.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious
person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse
mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid.
Notes to
Physician: Treat symptomatically and supportively.
Antidote: None reported.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish
surrounding fire.
Flash Point: Not available.
Autoignition
Temperature: Not available.
Explosion Limits, Lower:Not
available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Use only
in a well-ventilated area. Minimize dust generation and accumulation. Avoid
breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances. Keep
containers tightly closed.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Boric acid |
none listed |
none listed |
none listed
|
OSHA Vacated PELs: Boric acid: No
OSHA Vacated PELs are listed for this chemical.
Personal Protective
Equipment
Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear a chemical apron. Wear appropriate
protective clothing to prevent skin exposure.
Respirators: A
NIOSH/MSHA approved air purifying dust or mist respirator or European Standard
EN 149.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH: 5.2
(1% sol. at 20C)
Vapor Pressure: Not available.
Vapor
Density: Not available.
Evaporation Rate: Negligible.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point:339 deg F
Decomposition
Temperature:Not available.
Solubility: 4.9g/100g water at 20C.
Specific Gravity/Density:1.44 (Water=1)
Molecular
Formula:H3BO3
Molecular Weight:61.83
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions. Boric acid is a stable product, but when heated
it loses water, first forming Metaboric acid (HBO2), and on further heating it
is converted into Boric Oxide (B2O3).
Conditions to Avoid: High
temperatures, incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials: Reaction with strong
reducing agents, such as metal hydrides or alkali metals, will generate hydrogen
gas, which could create an explosion hazard., caustics (e.g. ammonia, ammonium
hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), acetic
anhydride, alkali carbonates.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, oxides of
boron.
Hazardous Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 10043-35-3: ED4550000; ED4560000
LD50/LC50:
CAS# 10043-35-3:
Oral,
mouse: LD50 = 3450 mg/kg;
Oral, rat: LD50 =
2660 mg/kg;
Oral, rat: LD50 = 2500
mg/kg;
Carcinogenicity:
CAS# 10043-35-3: Not listed by
ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information
available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No
information available.
Other Studies: None.
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Section 12 -
Ecological Information |
Ecotoxicity:
Water flea Daphnia: LC50 = 115.0-153.0 mg/L; 48 Hr.; Static ConditionFish:
Rainbow trout: LC50=150mg B/L; 24-day; Fish: Goldfish: LC50=46mg B/L; 7-day;
Mosquito fish (fresh water) TLm=1800 ppm/24H Mosquito fish (fresh water)
TLm=1800 ppm/24H
Environmental: Boric acid is a water-soluble white
powder that may, at high concentrations, cause damage to trees or vegetation by
root absorption.
Physical: No information available.
Other: None.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
|
US
DOT |
Canada
TDG |
| Shipping Name: |
Not reviewed. |
No information available. |
| Hazard Class: |
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| UN Number: |
|
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS#
10043-35-3 is listed on the TSCA inventory.
Health & Safety Reporting
List
None of the chemicals are on the
Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product
are under a Chemical Test Rule.
Section
12b
None of the chemicals are listed under
TSCA Section 12b.
TSCA Significant New Use
Rule
None of the chemicals in this material
have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding
RQs
None of the chemicals in this material
have an RQ.
SARA Section 302 Extremely Hazardous
Substances
None of the chemicals in this
product have a TPQ.
SARA Codes
CAS #
10043-35-3: acute, chronic.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does
not contain any hazardous air pollutants.
This
material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2
Ozone depletors.
Clean Water
Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are
listed as Priority Pollutants under the CWA.
None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this
product are considered highly hazardous by OSHA.
STATE
CAS# 10043-35-3 is not present
on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop
65
California No Significant Risk Level: None of the chemicals in
this product are listed.
European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
T
Risk Phrases:
R 60 May impair
fertility.
Safety Phrases:
S 45
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special
instructions before use.
WGK (Water
Danger/Protection)
CAS# 10043-35-3: 1
Canada - DSL/NDSL
CAS# 10043-35-3 is
listed on Canada's DSL List.
Canada -
WHMIS
This product has a WHMIS
classification of D2A.
Canadian Ingredient Disclosure
List
CAS# 10043-35-3 is listed on the
Canadian Ingredient Disclosure List.
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Section 16 -
Additional Information |
MSDS Creation Date:
5/03/1999
Revision #6 Date: 2/09/2004
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.